Home      News       Common knowledge of refractory bricks…

News

Common knowledge of refractory bricks

Clay bricks refer to clay products made of aluminum silicate materials with an Al2O3 content of 30% to 40%. Clay bricks are made of 50% soft clay and 50% hard clay clinker, mixed according to certain particle size requirements, formed, dried, and fired at high temperatures of 1300-1400 ℃. The mineral composition of clay bricks is mainly kaolinite (Al2O3 · 2SiO2 · 2H2O) and 6% to 7% impurities (oxides of potassium, sodium, calcium, titanium, and iron). The firing process of clay bricks mainly involves the continuous dehydration and decomposition of kaolinite to form mullite (3Al2O3 · 2SiO2) crystals. SiO2 and Al2O3 in clay bricks form eutectic low melting point silicates with impurities during the firing process, surrounding the mullite crystals.


Physical properties of clay refractory bricks
Clay bricks belong to weakly acidic refractory products, which can resist the erosion of acidic slag and acidic gases, but have slightly lower resistance to alkaline substances. Clay bricks have good thermal performance and are resistant to rapid cooling and heating. The fire resistance of clay bricks is comparable to that of silica bricks, reaching up to 1690-1730 ℃, but the softening temperature under load is more than 200 ℃ lower than that of silica bricks. Because in addition to high refractory mullite crystals, clay bricks also contain nearly half of low melting point amorphous glass phases.

Within the temperature range of 0-1000 ℃, the volume of clay bricks expands uniformly with increasing temperature, and the linear expansion curve approximates a straight line, with a linear expansion rate of 0.6% to 0.7%, which is only about half of that of silica bricks. When the temperature reaches 1200 ℃ and continues to rise, its volume will start to shrink from the maximum expansion value. The residual shrinkage of clay bricks leads to loose cracks in the mortar joints of the masonry, which is a major drawback of clay bricks. When the temperature exceeds 1200 ℃, the low melting point substances in the clay brick gradually melt, and the particles are tightly pressed against each other due to surface tension, resulting in volume shrinkage.


Application of clay bricks and refractory bricks
Due to the low load softening temperature of clay bricks, shrinkage occurs at high temperatures, and their thermal conductivity is 15% to 20% lower than that of silicon bricks. Their mechanical strength is also inferior to that of silicon bricks. Therefore, clay bricks can only be used for secondary parts of coke ovens, such as the sealing wall of the heat storage chamber, small flue lining bricks and heat storage chamber grid bricks, furnace door lining bricks, furnace top, and riser lining bricks.